The size of the skimmer should be based on the size of the tank where all the organics and waste are being produced. If you have a 250 gal tank with a 250 gal sump, the 250 gal tank is the one producing most of the waste and organics. The sump is really just adding water volume to the system not not really producing waste. So the skimmer should be rated for a 250 gal tank.
HTH,
Carlos
CoralVue